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by Keyword: N[sbnd]N bond cleavage


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Revilla-López, G., Sans, J., Casanovas, J., Bertran, O., Puiggalí, J., Turon, P., Alemán, C., (2020). Analysis of nitrogen fixation by a catalyst capable of transforming N2, CO2 and CH4 into amino acids under mild reactions conditions Applied Catalysis A: General 596, 117526

The processes related to the fixation of nitrogen in a catalyst able to produce glycine and alanine from a N2, CO2 and CH4 gas mixture at mild reaction conditions have been studied by combining experimental and theoretical investigations. Results have allowed to understand the role of different elements of the catalyst, which is constituted by permanently polarized hydroxyapatite (p-HAp), zirconia, and aminotris(methylenephosphonic acid) (ATMP). ATMP attracts N2 molecules towards the surface, maintaining them close to the zirconia and p-HAp components that are the most active from a catalytic point of view. On the other hand, the associative mechanism is thermodynamically favoured under mild reaction conditions with respect to the dissociative one, which is limited by the barrier associated to the Nsingle bondN bond cleavage. Because this reaction mechanism is similar to that employed in the nitrogen fixation by nitrogenase enzymes, these findings provide an opportunity to design new bioinspired catalysts.

Keywords: Artificial photosynthesis, Carbon fixation, Hydroxyapatite, N[sbnd]N bond cleavage